Pyridine complexes of some first-row transition metals

Terpyridine‐metal complexes of first row transition metals and electrochemical reduction of CO2 to CO

Density Functional Calculations on First-Row Transition Metals

The excitation energies and ionization potentials of the atoms in the first transition series are notoriously difficult to compute accurately. Errors in calculated excitation energies can range from 1–4 eV at the Hartree-Fock level, and errors as high as 1.5eV are encountered for ionization energies. In the current work we present and discuss the results of a systematic study of the first trans...

NQR Spectra of Chalcogenhalide Complexes of Some Transition Metals

für Naturforschung in cooperation with the Max Planck Society for the Advancement of Science under a Creative Commons Attribution 4.0 International License. Dieses Werk wurde im Jahr 2013 vom Verlag Zeitschrift für Naturforschung in Zusammenarbeit mit der Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. digitalisiert und unter folgender Lizenz veröffentlicht: Creative Commons Namen...

Systematic investigation of trigonal-bipyramidal cyanide-bridged clusters of the first-row transition metals.

Reactions between [M'(III)(CN)(6)](3-) anions (M' = Co, Cr, or Fe) and mononuclear complexes of M(II) ions (M = Cr, Mn, Co, Ni, or Zn) produce a family of pentanuclear clusters {[M(tmphen)(2)](3)[M'(CN)(6)](2)]}. The core of the clusters is formed by five metal ions that are bridged through six CN- linkers into a trigonal bipyramid, with M and M' ions occupying equatorial and axial positions of...

edu Third row transition metals for the treatment of cancer

Platinum compounds are a mainstay of cancer chemotherapy, with over 50% of patients receiving platinum. But there is a great need for improvement. Major features of the cisplatin mechanism of action involve cancer cell entry, formation mainly of intrastrand cross-links that bend and unwind nuclear DNA, transcription inhibition and induction of celldeath programmes while evading repair. Recently...